WS₂とTEMPOLラジカルのスピン依存電子移動の熱力学と動力学

Spin-Dependent Electron Transfer between WS₂ Conduction Electrons and TEMPOL Radicals

Abstract: We analyze the thermodynamics and spin dynamics of electron transfer from WS₂ conduction-band electrons to TEMPOL nitroxide radicals. Using standard reduction potentials at pH 7, we compute the reaction Gibbs energy and spontaneity. We quantify magnetic field effects (Δg mechanism) at 300 mT on radical-pair spin mixing, and discuss how exchang…