TEMPOLからアントラセンカチオンラジカルへの光誘起電子移動反応と磁場効果の詳細解析

Detailed Analysis of Photoinduced Electron Transfer from TEMPOL to Anthracene Radical Cation and Magnetic Field Effects

Abstract: A comprehensive analysis is presented for the photo-induced electron transfer from the TEMPOL radical (a nitroxide) to the anthracene cation radical (Ant^+•) in aqueous solution at room temperature. Reaction free energy is evaluated from redox potentials (in eV) to assess spontaneity. Electron paramagnetic resonance (EPR) g-factors of TEMPOL• a…