PAMAMデンドリマー内にルテニウム錯体触媒を入れ込むには？

Using dendrimer nanospaces to create an organic-solvent-like environment in water for ruthenium catalysis

Abstract: We explore the challenge of coordinating a ruthenium complex with tertiary amine ligands inside dendrimers in water. By tuning pH, the dendrimer’s interior can become hydrophobic, mimicking organic solvent conditions. We discuss why RuCl₃ fails in water, and how alternative Ru precursors (RuCl₂(DMSO)₄ or [Ru(NH₃)₆]³⁺) plus careful pH optimizat…