コバロキシムの配位子と水素生成助触媒への応用

Tuning cobalt cobaloxime catalysts for hydrogen evolution in artificial photosynthesis

Abstract: Cobalt–cobaloxime complexes are promising molecular catalysts for hydrogen evolution in artificial photosynthesis. This article discusses how species like [Co(dmgH)₂L₂] and [Co(dmgH)₂L] (dmgH = dimethylglyoxime) differ in charge, solubility, and catalytic behavior. We explain how ligand environments control complex charge and solvent compatibi…