テルピリジンの使い道(酸素生成反応助触媒)
Oxygen evolution using Ru-complex with 2,2':6',2''-terpyridine
Abstract: This article reviews the pioneering work by Prof. Ken Sakai and Prof. Shigeyuki Masaoka on mononuclear Ru-based water oxidation catalysts. We chronicle their 2009 breakthroughs with single-Ru catalysts, the evolution of ligand design (electronic tuning, steric control, second-sphere hydrogen bonding), synthetic protocols, mechanistic elucidati…


