光誘起電子移動を利用した螺旋主鎖ポリアニリン・ポリチオフェン合成の可能性
Towards Helical Polyaniline and Polythiophene via Photoinduced Electron Transfer Polymerization
Abstract: We explore the synthesis of helical-backbone polyaniline and polythiophene using photoinduced electron transfer (PET) polymerization. Visible-light photoredox catalysts (e.g. g-C₃N₄, Ru(bpy)32+–persulfate, Eosin Y–O₂) enable oxidative polymerizations. We discuss substituent designs (chiral side chains, axial chiral units, interactive functiona…
