疎水性溶媒中で観測されるカーボンナノチューブ吸収スペクトルの青方偏移とは何か
Why do SWCNT absorption spectra blue-shift in hydrophobic solvents?
Abstract: Single-walled carbon nanotubes (SWCNTs) exhibit strongly environment-dependent optical transition energies due to their one-dimensional excitonic nature. In particular, when SWCNTs are dispersed in low-dielectric, hydrophobic solvents such as hexane, their characteristic first and second sub-band excitonic absorption peaks (E<sub>11</sub> and …
